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Extra info for Amino Acids, Peptides and Proteins (SPR Amino Acids, Peptides, and Proteins (RSC))vol.16

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M. Charton and €3. I. Charton, J. Theor. ,1982, 99, 629. N . V. Kumar and G. Govil in 'Conformation in Biology', ed. R. Srinivasan and R. H. Sarma, Adenine Press, Guilderland, New York, 1983, p. 31 3. 272). 286 5 Chemical Studies of Amino Acids Racemization. - Papers describing mechanistic aspects of amino acid racemization argue in favour287 of a two-step process with abstraction of the methine proton being rate-determining. There is also evidence288 that racemization of L-[ l - 2 H ]alanine proceeds with significant internal return of the proton when catalysed by tyrosine phenol lyase and the amino acid racemase from Pseudomonas striata, supporting the idea that a single base is involved in the process.

1983, 267, 11; Anal. , 1983, 5 5 , 1805; Tetrahedron L e t t . , 1983, 24, 1509. 193 N. Watanabe, J. , 1983, 260, 75. 1 9 4 X . Xu, Q. Tang, and R. Wang, Huazue Xuebao, 1983, 41,262. 195 Yu. A. Zolotarev and N. F. Myasoedov, J . , 1983, 264, 377. 1 9 6 V . A. Shirokov, V. A. Tsyryapkin, L. V. Nedospasova, A. A. Kurganov, and V. A. Davankov, Bioorg. , 1983, 9 , 878. 1 9 7 T. Shiraiwa, Y . Ohmichi, K. Iwafuji, K. Fujimoto, and H. Kurokawa, Nippon Kagaku Kaishi, 1983, 1070 (Chem. , 1984, 100,7090).

T. Golding, and R. W. McCabe, J . Chem. , Perkin Trans. I , 1983, 2287. 215 C. G . Suresh and M. Vijayan, Int. J . Pept. , 1983, 22, 129. '02 A mino Acids 21 adopted. The head-to-tail arrangement seen in the crystal structure of L-ornithine L-aspartate is the first example for a mixed amino acid salt. Nuclear Magnetic Resonance Spectrometry. r. studies are now frequently performed and reported jointly, and this is reflected in the structure of this section. r. studies of amino acids and their derivatives are reviewed in order of increasing atomic number.

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